skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.

Explore Research Products in the PAR
It may take a few hours for recently added research products to appear in PAR search results.


  • Home
  • Search Results
  • Page 1 of 1

Search for: All records

Creators/Authors contains: "Giri, Samyadev"

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

  1. ; (, ChemRxiv)
    A visible light-mediated, I2-catalyzed intermolecular transformation of alkenes, conjugated dienes, styrenes and alkynes to isooxazoline and isoxazole motifs with a-nitrocarbonyls and analogs is reported. The reaction is also applicable to 1,1-disubstituted terminal, 1,2-disubstituted internal and trisubstituted alkenes, and tolerates a range of functional groups including epoxides, heterocycles, phosphates, free alcohols and thiocyanates. Mechanistic studies reveal that a-nitrocarbonyls are first converted to -carbonyl radicals followed by their conversion to acyl nitrile oxides, which subsequently undergo [3 + 2] dipolar cycloaddition reactions with the unsaturated molecules. 
    more » « less
    Full Text Available